|

Joseph
Warden received his Ph.D. in physical chemistry (specialty:
molecular spectroscopy) at the University of Minnesota under
the direction of James Bolton. After postdoctoral studies at
the Rijksuniversiteit, Leiden in the Netherlands (with L. N.
M. Duysens) and the University of California, Berkeley (Melvin
Calvin), Dr. Warden joined the chemistry faculty at Rensselaer.
Our research group applies the techniques of physical and
protein chemistry to study the structure and function of biological
oxidation-reduction complexes. Electron paramagnetic resonance
spectroscopy, time-resolved optical (laser) spectroscopy and
electroabsorption (Stark) spectroscopy are typical experimental
methodologies practiced in our laboratory.
Although a major focus of my laboratory is the elucidation
of the structure and function of the reaction-center protein
complexes that catalyze the initial light-driven steps in photosynthesis,
collaborative investigations include: characterization of the
structures and mechanism of radical products in irradiated ultrahigh
molecular weight polyethylene (polymer physical chemistry, medical
applications); oxygen radical metabolism in cellular processes
(aging and cell apoptosis) and function and structures of de
novo design proteins.

Charge Recombination
between P700+ and A1- Occurs Directly to the Ground State of
P700 in a Photosystem I Core Devoid of Fx, Fb and Fa. P. V.
Warren, J. H. Golbeck and J. T. Warden (1993) Biochemistry
32, 1835.
Investigation of
the Ammonium Acetate Inhibition of Oxygen Evolution by Photosystem
II. D. J. MacLachlan, J. H. A. Nugent, J. T. Warden and M. C.
W. Evans (1995) Biochim. Biophys. Acta 1188, 325-334.
Electron Spin Resonance
and Electrospray Ionization Mass Spectroscopic Studies of the
Interaction of Alkali and Alkaline Earth Cations with Manganese
Bis(Mu-Oxo) Dimers. C. P. Horwitz, J. T. Warden and S. T. Weintraub
(1996) Inorganica Chimica Acta 246, 311-320.
An Extended X-Ray
Absorption Fine Structure Study of bis(m-oxo) Bridged Dinuclear
Manganese Co-ordination Compounds Containing Alkali- and Alkaline-earth-metal
Cations in a Crown Ether Moiety. S. Turconi, C. P. Horwitz,
Y. Ciringh, S. T. Weintraub, J. T. Warden, J. H. A. Nugent and
M. C. W. Evans (1997) J. Chem. Soc., Dalton Trans. 4075
-4082.
An Exafs Study Of
Bis(Mu-Oxo) Bridged Dinuclear Manganese Coordination Compounds
As Models For The Manganese Complex Of Photosystem II. S. Turconi,
C. P. Horwitz, Y. Ciringh, S. T. Weintraub, J. T. Warden, J.
H. A. Nugent and M. C. W. Evans (1997) Journal De Physique
IV 7, 603-606.
|